1-Chloro-3,3,3-trifluoropropene

1-Chloro-3,3,3-trifluoropropene
Names
IUPAC name
1-Chloro-3,3,3-trifluoropropene
Other names
HFO-1233zd, HCFC-1233zd
Identifiers
2730-43-0 mixture of E- and Z- isomers
102687-65-0 E-isomer
99728-16-2 Z-isomer
3D model (Jmol) Interactive image
Properties
C3H2ClF3
Molar mass 130.49 g·mol−1
Appearance colorless liquid
Boiling point 20.8 °C (Z)
-18.5 °C (E)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

1-Chloro-3,3,3-trifluoropropene (HFO-1233zd) is the unsaturated chlorofluorocarbon with the formula HClC=C(H)CF3. This colorless gas is of interest as a refrigerant in air conditioners. The compound exists as E- and Z-isomers.[1] It is prepared by fluorination and dehydrohalogenation reactions starting with 1,1,1,3,3-pentachloropropane.[2]

References

  1. Cheryl Hogue (2011). "Replacing the Replacements". Chemical & Engineering News. 89 (49): 31–32. doi:10.1021/cen-v089n049.p031.
  2. Tung, Hseuh Sung; Ulrich, Kevin D.; Merkel, Daniel C. "Low-temperature catalytic fluorination process for the manufacture of 1-chloro-3,3,3-trifluoropropene from 1,1,1,3,3-pentachloropropane and hydrogen fluoride" U.S. (2005), US 6844475 B2 20050118 to Honeywell International Business Machines.
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