History of salt

Naturally formed salt crystals

Ancient method of boiling brine into pure salt in China

Salt, NaCl, is an ionic compound made of sodium and chloride ions. It has been important to humans for thousands of years, because all life has evolved to depend on it. Humans, like all life, need dietary salt to survive. Salt's ability to preserve food was a founding contributor to civilization. It helped to eliminate dependence on seasonal availability of food, and made it possible to ship some foods over long distances. However, salt was difficult to obtain, so it was a highly valued trade item, and considered a form of currency by certain peoples. Many salt roads, such as the via Salaria in Italy, had been established by the Bronze age.

All through history, availability of salt has been pivotal to civilization. In Britain, the suffix "-wich" in a placename means it was once a source of salt, as in Sandwich and Norwich. The Natron Valley was a key region that supported the Egyptian Empire to its north, because it supplied it with a kind of salt that came to be called by its name, natron. Today, salt is almost universally accessible, relatively cheap, and often iodized.

Sources

Salt comes from two main sources: sea water and the sodium chloride mineral halite (also known as rock salt). Rock salt occurs in vast beds of sedimentary evaporite minerals that result from the drying up of enclosed lakes, playas, and seas. Salt beds may be up to 350 m thick and underlie broad areas. In the United States and Canada extensive underground beds extend from the Appalachian basin of western New York through parts of Ontario and under much of the Michigan basin. Other deposits are in Texas, Ohio, Kansas, New Mexico, Nova Scotia, and Saskatchewan. In the United Kingdom underground beds are found in Cheshire and around Droitwich. Salzburg, Austria, was named "the city of salt" for its mines.^[1] High-quality rock salt was cut in medieval Transylvania, Maramureş and Southern Poland (Wieliczka). Tuzla in Bosnia and Herzegovina was named in Hungarian Só (salt) from the twelfth century on and later "place of salt" by Turks.

Salt is extracted from underground beds either by mining or by solution mining using water to dissolve the salt. In solution mining the salt reaches the surface as brine, from which the water is evaporated leaving salt crystals.

History

The Sečovlje Saltworks on the Northern Adriatic Sea were probably started in Antiquity and were first mentioned in 804 in the document on Placitum of Riziano.

Ancient world

Solnitsata, the earliest known town in Europe was built around a salt production facility. Located in present-day Bulgaria, archaeologists believe the town accumulated wealth by supplying salt throughout the Balkans.^[2]

Salt was of high value to the Hebrews, Greeks, the Chinese, Hittites^[3] and other peoples of antiquity. Aside from being a contributing factor in the development of civilization, salt was also used in the military practice of salting the earth by various peoples, beginning with the Assyrians . In the early years of the Roman Republic, with the growth of the city of Rome, roads were built to make transportation of salt to the capital city easier. An example was the Via Salaria (originally a Sabine trail), leading from Rome to the Adriatic Sea. The Adriatic, having a higher salinity due to its shallow depth, had more productive solar ponds compared with those of the Tyrrhenian Sea, much closer to Rome. The word "salary" comes from the Latin word for salt because the Roman Legions were sometimes paid in salt. They say the soldiers who did their job well were "worth their salt."^[4][5][6]

Vertical derricks and drilling rig from Qing dynasty Zigong, China extracting brine from deep underground wells.

During the late Roman Empire and throughout the Middle Ages salt was a precious commodity carried along the salt roads into the heartland of the Germanic tribes. Caravans consisting of as many as forty thousand camels traversed four hundred miles of the Sahara bearing salt to inland markets in the Sahel, sometimes trading salt for slaves: Timbuktu was a huge salt and slave market.

Salt in Chinese history was both a driver of technological development and a stable source of revenue for the imperial government.

In the Old Testament, Mosaic law calls for salt to be added to all burnt animal sacrifices (Lev. 2:13) and compares the priestly covenant between God and the kohen patrilineal descendants of Ahron to salt.

The Book of Ezra (550 BC to 450 BC) associated accepting salt from a person with being in that person's service. In Ezra 4:14, the adversaries of Ezra and company, in their letter of complaint to Artaxerxes I of Persia explain their loyalty to the King. When translated, it is either stated literally as "because we have eaten the salt of the palace" or more figuratively as "because we have maintenance from the king".

Salt is used as a metaphor in the Bible. In the New Testament, Matthew 5:13, Jesus said, "You are the salt of the earth". He added that if the salt loses its flavor, it is good for nothing but to be trampled. Jesus said this to show his disciples how valuable they were, and this saying is used today to describe someone who is of particular value to society. In addition, the preservative quality of salt is in view here to show how the disciples were called to preserve the society and the world around them from moral decay. On another occasion, according to the Gospels, Jesus commanded his followers to "...have salt within them."

In Luke 14:34-35 Jesus concludes a series of parables on the cost of following him with the parable of spent salt. It seems that those who follow him are to be like the salt. From this we learn that those who follow him should expect to be spent, as chunks of salt after much use. Furthermore, they should prepare to be useful until the end, for the long haul. In this parable, it is good to be used as salt and bad to become useless salt. This illustration ties in with the two preceding ones (Luke 14:28-33) of counting the cost: the disciples must prepare, by counting the cost, to be salty for as long as they are needed.

Cities and wars

Salt production on Læsø, Denmark (reconstruction)

Salt has played a prominent role in determining the power and location of the world's great cities. Liverpool rose from just a small English port to become the prime exporting port for the salt dug in the great Cheshire salt mines and thus became the entrepôt for much of the world's salt in the 19th century.^[1]

Salt created and destroyed empires. The salt mines of Poland led to a vast kingdom in the 16th century, only to be demolished when Germans brought in sea salt (which most of the world considered superior to rock salt). Venice fought and won a war with Genoa over salt. However, Genoese Christopher Columbus and Giovanni Caboto would later destroy the Mediterranean trade by introducing the New World to the market.^[1]

Cities, states and duchies along the salt roads exacted heavy duties and taxes for the salt passing through their territories. This practice even caused the formation of cities, such as the city of Munich in 1158, when the then Duke of Bavaria, Henry the Lion, decided that the bishops of Freising no longer needed their salt revenue.^[1]

The gabelle—a hated French salt tax—was enacted in 1286 and maintained until 1790. Because of the gabelles, common salt was of such a high value that it caused mass population shifts and exodus, attracted invaders and caused wars.^[1]

In American history, salt has been a major factor in outcomes of wars. In the Revolutionary War, the British used Loyalists to intercept Revolutionaries' salt shipments and interfere with their ability to preserve food.^[1] During the War of 1812, salt brine was used to pay soldiers in the field, as the government was too poor to pay them with money. Before Lewis and Clark set out for the Louisiana Territory, President Jefferson in his address to Congress mentioned a mountain of salt, 180 miles long and 45 wide, supposed to lie near the Missouri River, which would have been of immense value, as a reason for their expedition.^[7]

During India's independence movement, Mohandas Gandhi organized the Salt Satyagraha protest to demonstrate against the British salt tax.^[1]

English "-wich towns"

Wich and wych are names associated (but not exclusively) with brine springs or wells in England. Originally derived from the Latin vicus, meaning "place", by the 11th century use of the 'wich' suffix in placenames was associated with places with a specialised function including that of salt production.^[8] Several English places carry the suffix and are historically related to salt, including the four Cheshire 'witches' of Middlewich, Nantwich, Northwich and Leftwich (a small village south of Northwich), and Droitwich in Worcestershire. Middlewich, Nantwich, Northwich and Droitwich are known as the "Domesday Wiches" due to their mention in the Domesday Book, "an indication of the significance of the salt-working towns in the economy of the region, and indeed of the country".^[8]

Salt trade

Monopolies over salt production and trade were essential aspects of government revenue in imperial China and most of the 20th century.

During modern times, it became more profitable to sell salted food than pure salt. Thus sources of food to salt went hand in hand with salt making. The British controlled saltworks in the Bahamas as well as North American cod fisheries.^[1] The search for oil in the late 19th and early 20th centuries used the technology and methods pioneered by salt miners, even to the degree that they looked for oil where salt domes were located.^[1]

Salt production

A 'zouthuisje', i.e. little salt-house, used for salt making today. Many of these structures can be found near Twekkelo in Twente

On an industrial scale, salt is produced in one of two principal ways: the evaporation of salt water (brine) or by mining. Evaporation can either be solar evaporation^[9] or using some heating device.

Solar evaporation of seawater

In the correct climate (one for which the ratio of evaporation to rainfall is suitably high) it is possible to use solar evaporation of sea water to produce salt. Brine is evaporated in a linked set of ponds until the solution is sufficiently concentrated by the final pond so that the salt crystallizes on the pond's floor.

Open pan production from brine

One of the traditional methods of salt production in more temperate climates is using open pans.^[10] In open-pan production, salt brine is heated in large, shallow open pans. The earliest examples of this date back to prehistoric times and the pans were made of either a type of ceramic called briquetage, or lead. Later examples were made from iron. This change coincided with a change from wood to coal for the purpose of heating the brine.^[11] Brine would be pumped into the pans and concentrated by the heat of the fire burning underneath. As crystals of salt formed, these would be raked out and more brine added.

Closed pan production under vacuum

Container of Saxa salt, produced using vacuum extraction

The open pan salt works has effectively been replaced with a closed pan system where the brine solution is evaporated under a partial vacuum.^[12]

Salt mines

In the second half of the 19th century, industrial mining and new drilling techniques made the discovery of more and deeper deposits possible, increasing mine salt's share of the market. Although mining salt was generally more expensive than extracting it from brine via solar evaporation of seawater, the introduction of this new source reduced the price of salt due to a reduction of monopolization. Extraction of salt from brine is still heavily used, for example, vacuum salt produced by British Salt in Middlewich has 57% of the UK market ^[13] for salt used in cooking.

Other salt uses

The earliest systematic exposition of the different kinds of salts, its uses, and the methods of its extraction was published in China around 2700 BCE. Hippocrates encouraged his fellow healers to use salt water to heal various ailments by immersing their patients in sea water. The ancient Greeks continued this, and in 1753, English author and physician Dr. Charles Russel published The Uses of Sea Water.

See also

• Alberger process
• Bath salts
• International Salt Co. v. United States
• Iodised salt
• Garum
• Fish sauce
• Salt in Cheshire
• Salt March
• Salt Riot
• Sodium chloride

References

Further reading

• Salt Institute History of Salt at the Wayback Machine (archived March 3, 2009)
• The Role of Salt in Eastern North American Prehistory

External links

• Graphic showing mineral needs of an average American (pdf)
• Richard Cowen, The importance of salt (draft book chapter)