Hydrobromic acid

Hydrobromic acid
Names
Other names
Hydronium bromide
Identifiers
10035-10-6 YesY
3D model (Jmol) Interactive image
ChEBI CHEBI:47266 YesY
ChemSpider 255 YesY
ECHA InfoCard 100.030.090
EC Number 233-113-0
PubChem 260
RTECS number MW3850000
UNII 3IY7CNP8XJ N
Properties
HBr
Molar mass 80.91
Appearance colorless/faint yellow liquid
Odor acrid
Density 1.49 g/cm3 (48% w/w aq.)
Melting point −11 °C (12 °F; 262 K) (47–49% w/w aq.)
Boiling point 122 °C (252 °F; 395 K) at 700 mmHg (47–49% w/w aq.)
221 g/100 mL (0 °C)
204 g/100 mL (15 °C)
130 g/100 mL (100 °C)
Acidity (pKa) −9[1]
Viscosity 0.84 cP (-75 °C)
Thermochemistry
29.1 J/K mol
198.7 J/K mol
-36.3 kJ/mol
Hazards
Safety data sheet ICSC 0282
Corrosive (C)
R-phrases R34, R37
S-phrases (S1/2), S7/9, S26, S45
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
0
3
0
Flash point Non-flammable
Related compounds
Other anions
 Hydrofluoric acid
Hydrochloric acid
Hydroiodic acid
Related compounds
 Hydrogen bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Hydrobromic acid is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C and contains 47.6% HBr by weight, which is 8.89 mol/L. Hydrobromic acid has a pKa of −9, making it a stronger acid than hydrochloric acid, but not as strong as hydroiodic acid. Hydrobromic acid is one of the strongest mineral acids known.

Uses

Hydrobromic acid is mainly used for the production of inorganic bromides, especially the bromides of zinc, calcium, and sodium. It is a useful reagent for generating organobromine compounds. Certain ethers are cleaved with HBr. It also catalyzes alkylation reactions and the extraction of certain ores. Industrially significant organic compounds prepared from hydrobromic acid include allyl bromide, tetrabromobis(phenol), and bromoacetic acid.[2]

Synthesis

Hydrobromic acid can be prepared in the laboratory via the reaction of Br2, SO2, and water.[3]

Br2 + SO2 + 2 H2O → H2SO4 + 2 HBr

More typically laboratory preparations involve the production of anhydrous HBr, which is then dissolved in water.

Hydrobromic acid has commonly been prepared industrially by reacting bromine with either sulfur or phosphorus and water. However, it can also be produced electrolytically.[3] It can also be prepared by treating bromides with non-oxidising acids like phosphoric or acetic acids.

Alternatively the acid can be prepared with dilute (5.8M) sulfuric acid and potassium bromide:[4]

H2SO4 + KBr → KHSO4 + HBr

Using more concentrated sulfuric acid or allowing the reaction solution to exceed 75 °C further oxidizes HBr to bromine gas. The acid is further purified by filtering out the KHSO4 and by distilling off the water until the solution reaches an azeotrope (≈ 126 °C at 760 torr). The yield is approximately 85%.[4]

Hydrobromic acid is available commercially in various concentrations and purities.

References

  1. ↑ Bell, R.P. The Proton in Chemistry, 2nd ed., Cornell University Press, Ithaca, NY, 1973.
  2. ↑ Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. (2005), "Bromine Compounds", Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, doi:10.1002/14356007.a04_405
  3. 1 2 Scott, A. (1900). "Preparation of Pure Hydrobromic Acid". Journal of the Chemical Society, Transactions. 77: 648–651. doi:10.1039/ct9007700648.
  4. 1 2 Brauer, Georg (1963). Handbook of Preparative Inorganic Chemistry Vol. 1, 2nd Ed. Newyork: Academic Press. p. 285. ISBN 978-0121266011.

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