Ionic polymerization

IUPAC definition

Chain polymerization in which active centers are ions or ion pairs.

Note 1: Usually the chain-ends are ions, although ions can also be located

on the monomer molecules, as in an activated-monomer polymerization.

Note 2: The ions may also be present in the form of higher aggregates

that usually are less reactive than non-aggregated species.

Modified from the earlier definition.[1]

Penczek S.; Moad, G. Pure Appl. Chem., 2008, 80(10), 2163-2193

Ionic polymerization is a chain-growth polymerization in which active centers are ions or ion pairs.[2] It can be considered as an alternative to radical polymerization, and may refer to anionic polymerization or cationic polymerization.[3]

References

  1. ↑ Jenkins, A. D.; Kratochvíl, P.; Stepto, R. F. T.; Suter, U. W. (1996). "Glossary of basic terms in polymer science (IUPAC Recommendations 1996)". Pure and Applied Chemistry. 68: 2287–2311. doi:10.1351/pac199668122287.
  2. ↑ Penczek, S.; Moad, G. (2008). "Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)". Pure and Applied Chemistry. 80: 2163–2193. doi:10.1351/pac200880102163.
  3. ↑ Chang, Feng-Chi. "Ionic Polymerization: Anionic and Cationic Polymerization" (PDF). Polymer Research Center, National Chiao Tung University. Retrieved 27 May 2013.


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