Palladium(II) nitrate

Palladium(II) nitrate
Names
IUPAC name
Palladium(II) nitrate
Other names
Palladium nitrate
Palladous nitrate
Identifiers
10102-05-3 YesY
3D model (Jmol) Interactive image
ChemSpider 23306 YesY
ECHA InfoCard 100.030.228
PubChem 24932
UNII 5G27LBZ05U YesY
Properties
Pd(NO3)2
Molar mass 230.43 g/mol
Appearance red-brown solid
Melting point Decomposes >100 °C
Soluble
Hazards
Main hazards Irritant, possibility of allergic reaction
Flash point Non-flammable
Related compounds
Other anions
 Palladium(II) chloride
Other cations
 Nickel(II) nitrate
Related compounds
 Silver nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Palladium(II) nitrate is the inorganic compound with the formula Pd(NO3)2. It is a red-brown deliquescent solid. As a solution in nitric acid, it catalyzes the conversion of alkenes to dinitrate esters. Its pyrolysis affords palladium oxide.[1]

Preparation

Palladium nitrate may be prepared by dissolving palladium oxide hydrate in dilute nitric acid followed by crystallization. The nitrate crystallizes as yellow-brown deliquescent prisms. Alternatively, the compound may be obtained by treating palladium metal with nitric acid.

References

  1. ↑ Timothy T. Wenzel "Palladium(II) Nitrate" Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley & Sons. doi: 10.1002/047084289X.rp013
Salts and covalent derivatives of the Nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4− C N O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3 Co(NO3)2,
Co(NO3)3		 Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2		 Tl(NO3)3 Pb(NO3)2 Bi(NO3)3
BiO(NO3)		 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce(NO3)3,
Ce(NO3)4		 Pr Nd Pm Sm Eu Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr
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