Dielectric elastomers

Working principle of dielectric elastomer actuators. An elastomeric film is coated on both sides with electrodes. The electrodes are connected to a circuit. By applying a voltage the electrostatic pressure acts. Due to the mechanical compression the elastomer film contracts in the thickness direction and expands in the film plane directions. The elastomer film moves back to its original position when it is short-circuited.

Dielectric elastomers (DEs) are smart material systems that produce large strains. They belong to the group of electroactive polymers (EAP). DE actuators (DEA) transform electric energy into mechanical work. They are lightweight and have a high elastic energy density. They have been investigated since the late 1990s. Many prototype applications exist. Every year, conferences are held in the US[1] and Europe.[2]

Working principles

A DEA is a compliant capacitor (see image), where a passive elastomer film is sandwiched between two compliant electrodes. When a voltage is applied, the electrostatic pressure arising from the Coulomb forces acts between the electrodes. The electrodes squeeze the elastomer film. The equivalent electromechanical pressure is twice the electrostatic pressure and is given by:

where is the vacuum permittivity, is the dielectric constant of the polymer and is the thickness of the elastomer film. Usually, strains of DEA are in the order of 10–35%, maximum values reach 300% (the acrylic elastomer VHB 4910, commercially available from 3M, which also sports a high elastic energy density and a high electrical breakdown strength.)

Ionic

Replacing the electrodes with soft hydrogels allows ionic transport to replace electron transport. Aqueous ionic hydrogels can deliver potentials of multiple kilovolts, despite the onset of electrolysis at below 1.5 V.[3][4]

The difference between the capacitance of the double layer and the dielectric leads to a potential across the dielectric that can be millions of times greater than that across the double layer. Potentials in the kilovolt range can be realized without electrochemically degrading the hydrogel.[3][4]

Deformations are well controlled, reversible, and capable of high-frequency operation. The resulting devices can be perfectly transparent. High-frequency actuation is possible. Switching speeds are limited only by mechanical inertia. The hydrogel's stiffness can be thousands of times smaller than the dielectric's, allowing actuation without mechanical constraint across a range of nearly 100% at millisecond speeds. They can be biocompatible.[3][4]

Remaining issues include drying of the hydrogels, ionic build-up, hysteresis, and electrical shorting.[3][4]

Early experiments in semiconductor device research relied on ionic conductors to investigate field modulation of contact potentials in silicon and to enable the first solid-state amplifiers. Work since 2000 has established the utility of electrolyte gate electrodes. Ionic gels can also serve as elements of high-performance, stretchable graphene transistors.[4]

Materials

Films of carbon powder or grease loaded with carbon black were early choices as electrodes for the DEAs. Such materials have poor reliability and are not available with established manufacturing techniques. Improved characteristics can be achieved with liquid metal, sheets of graphene, coatings of carbon nanotubes, surface-implanted layers of metallic nanoclusters and corrugated or patterned metal films.[4][5]

These options offer limited mechanical properties, sheet resistances, switching times and easy integration. Silicones and acrylic elastomers are other alternatives.

The requirements for an elastomer material are:

Mechanically prestretching the elastomer film offers the possibility of enhancing the electrical breakdown strength. Further reasons for prestretching include:

The elastomers show a visco-hyperelastic behavior. Models that describe large strains and viscoelasticity are required for the calculation of such actuators.

Materials used in research include graphite powder, silicone oil / graphite mixtures, gold electrodes. The electrode should be conductive and compliant. Compliance is important so that the elastomer is not constrained mechanically when elongated.[4]

Films of polyacrylamide hydrogels formed with salt water can be laminated onto the dielectric surfaces, replacing electrodes.[4]

DEs based on silicone (PDMS) and natural rubber are promising research fields.[6] Properties such as fast response times and efficiency are superior using natural rubber based DEs compared to VHB (acrylic elastomer) based DEs for strains under 15%.[7]

Configurations

Configurations include:

Applications

Dielectric elastomers offer multiple potential applications with the potential to replace many electromagnetic actuators, pneumatics and piezo actuators. A list of potential applications include:

  • Haptic Feedback
  • Pumps
  • Valves
  • Robotics
  • Active origami-inspired structure[8]
  • Prosthetics
  • Power Generation
  • Active Vibration Control of Structures
  • Optical Positioners such for auto-focus, zoom, image stabilization
  • Sensing of force and pressure
  • Active Braille Displays
  • Speakers
  • Deformable surfaces for optics and aerospace
  • Energy Harvesting
  • Noise-canceling windows[4]
  • Display-mounted tactile interfaces[4]
  • Adaptive optics[4]

References

  1. ↑ "Conference Detail for Electroactive Polymer Actuators and Devices (EAPAD) XV". Spie.org. 2013-03-14. Retrieved 2013-12-01.(registration required)
  2. ↑ European conference
  3. 1 2 3 4 Keplinger, C.; Sun, J. -Y.; Foo, C. C.; Rothemund, P.; Whitesides, G. M.; Suo, Z. (2013). "Stretchable, Transparent, Ionic Conductors". Science. 341 (6149): 984–7. doi:10.1126/science.1240228. PMID 23990555.
  4. 1 2 3 4 5 6 7 8 9 10 11 Rogers, J. A. (2013). "A Clear Advance in Soft Actuators". Science. 341 (6149): 968–969. doi:10.1126/science.1243314. PMID 23990550.
  5. ↑ Liu, Yang; Gao, Meng; Mei, Shengfu; Han, Yanting; Liu, Jing (2013). "Ultra-compliant liquid metal electrodes with in-plane self-healing capability for dielectric elastomer actuators". Applied Physics Letters. 103 (6): 064101. doi:10.1063/1.4817977.
  6. ↑ Madsen, Frederikke B.; Daugaard, Anders E.; Hvilsted, Søren; Skov, Anne L. (2016-03-01). "The Current State of Silicone-Based Dielectric Elastomer Transducers". Macromolecular Rapid Communications. 37 (5): 378–413. doi:10.1002/marc.201500576. ISSN 1521-3927. PMID 26773231.
  7. ↑ Koh, S. J. A.; Keplinger, C.; Li, T.; Bauer, S.; Suo, Z. (2011-02-01). "Dielectric Elastomer Generators: How Much Energy Can Be Converted #x003F;". IEEE/ASME Transactions on Mechatronics. 16 (1): 33–41. doi:10.1109/TMECH.2010.2089635. ISSN 1083-4435.
  8. 1 2 "Investigating the performance and properties of dielectric elastomer actuators as a potential means to actuate origami structures". Smart Materials and Structures. 23: 094003. doi:10.1088/0964-1726/23/9/094003.

Further reading

External links

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