Picture |
Viceroy |
From |
Until |
Monarch |
 | Don Antonio de Mendoza, Marquis of Mondéjar, Count of Tendilla | 14 November 1535 | 25 November 1550 |  Charles I |
 | Don Luís de Velasco, | 25 November 1550 | 31 July 1564 |
 | Francisco Ceinos, Dean of the Audiencia | 1 August 1564 | 19 October 1566 |  Philip II |
| Don Gastón Carrillo de Peralta y Bosquete, Third Marquis of Falces | 19 October 1566 | 11 November 1567 |
 | Licenciado Alonso de Muñoz and Licenciado Luís Carrillo | 11 November 1567 | April 1568 |
 | Licenciado Alonso de Muñoz | April 1568 | 14 April 1568 |
 | Francisco Ceinos, Dean of the Audiencia | 14 April 1568 | 4 November 1568 |
 | Don Martín Enríquez de Almanza | 5 November 1568 | 4 October 1580 |
| Don Lorenzo Suárez de Mendoza, Fourth Count of La Coruña | 4 October 1580 | 19 June 1583 |
 | Luís de Villanueva y Zapata, Dean of the Audiencia | 19 June 1583 | 24 September 1584 |
| Pedro de Moya y Contrerás (Archbishop of Mexico) | 25 September 1584 | 17 October 1585 |
| Don Álvaro Manrique de Zúñiga First Marquis of Villamanrique | 17 October 1585 | 27 January 1590 |
| Don Luís de Velasco Marquis of Salinas | 27 January 1590 | 5 November 1595 |
| Don Gaspar de Zúñiga Acevedo y Fonseca, Fifth Count of Monterrey | 5 November 1595 | 27 October 1603 |
| Don Juan de Mendoza y Luna, Marquis of Montesclaros | 27 October 1603 | 2 July 1607 |  Philip III |
| Don Luís de Velasco, Marquis of Salinas | 2 July 1607 | 19 June 1611 |
| García Guerra, O.P. (Archbishop of Mexico) | 19 June 1611 | 22 February 1612 |
| Pedro Otárola, Dean of the Audiencia | 22 February 1612 | 18 October 1612 |
| Don Diego Fernández de Córdoba, Marquis of Guadalcázar and Count of Posadas | 18 October 1612 | 14 March 1621 |
 | Paz de Valecillo, Dean of the Audiencia | 14 March 1621 | 11 September 1621 |
| Don Diego Carrillo de Mendoza y Pimentel, First Marquis of Gélves | 12 September 1621 | 1 November 1624 |  Philip IV |
Vacant Due to the discrepancy on the arrival of successor Viceroy from 1 November to 3 November 1624. |
| Don Rodrigo Pacheco y Osorio de Toledo, Third Marquis of Cerralvo | 3 November 1624 | 16 September 1635 |
| Don Lope Díez de Aux de Armendáriz, Marquis of Cadereyta | 16 September 1635 | 28 August 1640 |
| Don Diego Roque López Pacheco Cabrera y Bobadilla, Seventh Duke of Escalona, Seventh Marquis of Villena and Seventh Count of Xiquena | 28 August 1640 | 10 June 1642 |
| DonJuan de Palafox y Mendoza (Bishop of Puebla) | 10 June 1642 | 23 November 1642 |
| Don García Sarmiento de Sotomayor, Second Count of Salvatierra and Marquis of Sobroso | 23 November 1642 | 14 May 1648 |
| Marcos de Torres y Rueda (Bishop of Yucatan) | 15 May 1648 | 22 April 1649 |
| Matías de Peralta, Dean of the Audiencia | 22 April 1649 | 28 June 1650 |
| Don Luis Enríquez de Guzmán, Ninth Count of Alba de Liste and Marquis of Villaflor | 28 June 1650 | 15 August 1653 |
| Don Francisco Fernández de la Cueva, Eighth Duke of Alburquerque, Marquis of Cuéllar, Count of Ledesma and of Huelma | 15 August 1653 | 16 September 1660 |
| Don Juan de Leyva de la Cerda, Count of Baños and Marquis of Leyva and of Ladrada | 16 September 1660 | 29 June 1664 |
| Diego Osorio de Escobar y Llamas (Bishop of Puebla) | 29 June 1664 | 15 October 1664 |
| Don Antonio Sebastián de Toledo Molina y Salazar, Second Marquis of Mancera | 16 October 1664 | 20 November 1673 |
| Don Pedro Nuño Colón de Portugal y Castro, Sixth Duke of Veragua, Sixth Marquis of Jamaica and Sixth Count of Gelves | 20 November 1673 | 13 December 1673 |  Charles II |
| Payo Enríquez de Rivera Manrique, O.S.A. (Bishop of Guatemala and Archbishop of Mexico) | 13 December 1673 | 7 November 1680 |
| Don Tomás Antonio Manuel Lorenzo de la Cerda y Aragón Third Marquis of La Laguna de Camero Viejo | 7 November 1680 | 16 June 1686 |
| Don Melchor Portocarrero y Lasso de la Vega, Third Count of Monclova | 16 June 1686 | 20 November 1688 |
| Don Gaspar Melchor Baltasar de la Cerda Silva Sandoval y Mendoza, Eighth Count of Galve, Lord of Salcedón and Tortola | 20 November 1688 | 27 February 1696 |
| Juan de Ortega Cano Montañez y Patiño (Bishop of Durango, Guatemala, Michoacán and Archbishop of Mexico) | 27 February 1696 | 18 December 1696 |
| Don José Sarmiento y Valladares, Count of Moctezuma and of Tula | 18 December 1696 | 4 November 1701 |
| Juan de Ortega Cano Montañez y Patiño (Archbishop of Mexico) | 4 November 1701 | 27 November 1702 | _-_Google_Art_Project.jpg) Philip V |
| Don Francisco V Fernández de la Cueva Enríquez y Fernández de la Cueva, Tenth Duke of Alburquerque and Marquis of Cuéllar | 27 November 1702 | 13 November 1710 |
| Don Fernando de Alencastre Noroña y Silva, First Duke of Linares and Marquis of Valdefuentes | 13 November 1710 | 16 July 1716 |
| Don Baltasar de Zúñiga Guzmán Sotomayor y Mendoza, Duke of Arión and Marquis of Valero | 16 July 1716 | 15 October 1722 |
| Don Juan de Acuña y Bejarano, Second Marquis of Casa Fuerte | 15 October 1722 | 17 March 1734 |  Louis I From 1700–1724, Philip V of Spain was the king; then from 1724–1746. Louis I only reigned in 1724. |
| Juan Antonio de Vizarrón y Eguiarreta (Archbishop of Mexico) | 17 March 1734 | 17 August 1740 | _-_Google_Art_Project.jpg) Philip V |
| Don Pedro de Castro Figueroa y Salazar, First Duke of La Conquista and First Marquis of Gracia Real | 17 August 1740 | 22 August 1741 |
| Pedro Malo de Villavicencio, President of the Audiencia | 23 August 1741 | 2 November 1742 |
| Don Pedro Cebrián y Agustín, Fifth Count of Fuenclara | 3 November 1742 | 9 July 1746 |
| Don Juan Francisco de Güemes y Horcasitas, First Count of Revillagigedo | 9 July 1746 | 9 November 1755 |  Ferdinand VI |
| Don Agustín de Ahumada y Villalón, Marquis of Amarillas | 10 November 1755 | 5 February 1760 |
| Francisco Antonio de Echávarri, Dean of the Audiencia | 5 February 1760 | 28 April 1760 |
| Francisco Cajigal de la Vega | 28 April 1760 | 5 October 1760 |  Charles III |
| Don Joaquín de Montserrat, Marquis of Cruillas | 5 October 1760 | 24 August 1766 |
| Don Carlos Francisco de Croix, Marquis of Croix | 24 August 1766 | 22 September 1771 |
| Don Antonio María de Bucareli y Ursúa, Marquis of Valleheroso and Count of Jerena | 22 September 1771 | 9 April 1779 |
| Francisco Romá y Rosell, Regent of the Audiencia | 10 April 1779 | 22 August 1779 |
| Martín de Mayorga Ferrer, Captain General of Guatemala | 23 August 1779 | 28 April 1783 |
| Matías de Gálvez y Gallardo, Captain General of Guatemala | 28 April 1783 | 20 October 1784 |
| Vicente de Herrera y Rivero, Regent of the Audiencia | 20 October 1784 | 17 June 1785 |
| Don Bernardo de Gálvez y Madrid, Viscount of Galveston and Count of Gálvez | 17 June 1785 | 30 November 1786 |
| Eusebio Sánchez Pareja y Beleño Regent of the Audiencia | 30 November 1786 | 8 May 1787 |
| Alonso Núñez de Haro y Peralta (Archbishop of Mexico) | 8 May 1787 | 16 August 1787 |
| Manuel Antonio Flores Maldonado Martínez Ángulo y Bodquín | 16 August 1787 | 16 October 1789 |
 | Don Juan Vicente de Güemes Pacheco de Padilla y Horcasitas, Second Count of Revillagigedo | 17 October 1789 | 11 July 1794 |  Charles IV |
 | Don Miguel de la Grúa Talamanca de Carini y Branciforte, First Marquis of Branciforte | 12 July 1794 | 31 May 1798 |
 | Don Miguel José de Azanza Alegría, Duke of Santa Fe | 31 May 1798 | 30 April 1800 |
| Félix Berenguer de Marquina | 30 April 1800 | 4 January 1803 |
| José de Iturrigaray | 4 January 1803 | 16 September 1808 |
| Pedro de Garibay | 16 September 1808 | 19 July 1809 |  Joseph Bonaparte |
| Francisco Javier de Lizana y Beaumont (Archbishop of Mexico) | 19 July 1809 | 8 May 1810 | _by_Goya.jpg) Ferdinand VII |
| Pedro Catani | 8 May 1810 | 14 September 1810 |
| Don Francisco Javier Venegas, Marquess of Reunión and of New Spain | 14 September 1810 | 4 March 1813 |
| Don Félix María Calleja del Rey, First Count of Calderón | 4 March 1813 | 20 September 1816 |
| Don Juan Ruiz de Apodaca, First Count of Venadito | 20 September 1816 | 5 July 1821 |
| Francisco Novella Azabal Pérez y Sicardo | 15 July 1821 | 21 July 1821 |
| Juan O'Donojú | 21 July 1821 | 28 September 1821 |